个人简介
顾正洋,理学博士,讲师。先后主持国家自然科学基金青年基金、江苏省教育厅面上项目;发表SCI/EI收录论文13余篇;授权发明专利2件;获苏州市自然科学优秀学术论文二等奖1项。
研究方向
过渡金属催化异腈化学、过渡金属催化氮烯羰化转化等。
荣誉及获奖情况
2016年,苏州市自然科学优秀学术论文二等奖
教育背景与工作履历
2009.09-2013.06,苏州大学,化学,学士
2013.09-2018.06,苏州大学,有机化学,博士
2018.10-至今,盐城工学院,纺织服装学院,讲师
主持的教科研项目
[1] 双金属协同催化氮烯的不对称羰基化反应研究,国家自然科学基金委员会,2021.01-2023.12。
[2] 双金属协同催化氮烯的不对称羰基化反应研究,江苏省教育厅,2020.12-2022.12。
代表性教科研成果
[知识产权]
[1] 一种合成磺酰基酮酰胺的新方法,发明专利,ZL202010116633.4。
[2] 一种构建酰胺键的新方法,发明专利,201910124357.3。
[科研论文]
[1] Zheng-Yang Gu, et al, [3 + 1 + 1] Cyclization of vinyl oxiranes with azides and CO by tandem palladium catalysis: efficient synthesis of oxazolidinones. Organic Chemistry Frontiers, 2021.
[2] Zheng-Yang Gu, et al, Catalytic synthesis of functionalized amidines via cobalt-carbene radical coupling with isocyanides and amines. Organic Chemistry Frontiers, 2021.
[3] Zheng-Yang, Gu, et al, Intermolecular C-H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis, Synthesis, 2021.
[4] Zheng-Yang Gu, et al, Pd-catalyzed amidation of 1,3-diketones with CO and azides via a nitrene intermediate. Chemical Communications, 2020.
[5] Si-Wen Yuan, Zheng-Yang Gu* et al, Intermolecular C-H amidation of (hetero)arenes to produce amides through rhodium-catalyzed carbonylation of nitrene intermediates. Angewandte Chemie International Edition, 2019.
[6] Zheng-Yang Gu, et al, Cobalt(II)-catalyzed bis-isocyanides insertion reactions with boric acids and sulfonyl azides via nitrene radical coupling. Chinese Journal of Chemistry, 2018.
[7] Zheng-Yang Gu, et al, Cobalt(II)-Catalyzed Synthesis of Sulfonyl Guanidines via Nitrene Radical Coupling with Isonitriles: A Combined Experimental and Computational Study, ACS Catalysis, 2017.
[8] Zheng-Yang Gu et al, Cobalt(II)-catalyzed bis-isocyanide insertion reactions with sulfonyl azides via nitrene radicals: chemoselective synthesis of sulfonylamidyl amide and 3-imine indole derivatives, Chemical Communications, 2017.
联系方式
邮箱:zhygu@foxmail.com
电话:0515-88298132